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CHAPTER 2 CONTENTS
2.1 MONOSACCHARIDES
2.1.1 Nomenclature and Structure Relationships
2.1.2 Ring Forms of Sugars
2.1.3 Glycosides
2.1.3.1 Glycosylation using alcohols
2.1.3.2 Biological alternatives to acid catalysis
2.1.3.3 Synthetic approaches
2.2 DISACCHARIDES
2.2.1 Reducing Disaccharides
2.2.2 Non-reducing Disaccharides
2.3 OLIGOSACCHARIDES
2.3.1 Trisaccharides
2.3.2 Tetrasaccharides
2.3.3 Higher Oligosaccharides
2.3.4 Cyclodextrins
2.4 POLYSACCHARIDES
2.4.1 Plant Polysaccharides
2.4.1.1 Homoglycans
2.4.1.2 Heteroglycans
2.4.2 Polysaccharides from Algae
2.4.2.1 Red algae
2.4.2.2 Brown algae
2.4.2.3 Green algae
2.4.3 Fungal Polysaccharides
2.4.3.1 Glucans
2.4.3.2 Mannans
2.4.3.3 Chitin
2.4.3.4 Galactomannans
2.4.3.5 Other fungal polysaccharides
2.4.4 Bacterial Polysaccharides
2.4.4.1 Exopolysaccharides
2.4.4.2 Components of bacterial cell walls
2.5 GLYCOSIDES AND GLYCOCONJUGATES
2.5.1 Cardiac and Phenolic Glycosides
2.5.2 Glycolipids
2.5.3 Glycoproteins
2.5.3.1 Structural classification
2.5.4 Proteoglycans
2.5.4.1 Glycosaminoglycans
2.5.4.2 Plant extensins and AGP's
2.5.5 Enzymes and Lectins
2.5.5.1 Enzymes
2.5.5.2 Lectins
2.5.6 Other Polysaccharides
2.6 CONFORMATIONS
2.6.1 Chemical and Physical Evidence for Configurations and Conformations in Solution
2.6.1.1 Chemical evidences for sugar conformations
2.6.1.2 NMR spectroscopy
2.6.2 Conformations of Oligo- and Polysaccharides
2.6.2.1 General
2.6.2.2 Oligosaccharides
2.6.2.3 Polysaccharides
2.6.3 X-Ray Analysis and Molecular Modelling. Electron Microscopy and AFM
CHAPTER 3 CONTENTS
3.1 CHEMISTRY OF MONOSACCHARIDES AND DERIVED COMPOUNDS
3.1.1 Reactions at Anomeric Centres
3.1.1.1 Reduction
3.1.1.2 Oxidation
3.1.1.3 Glycosidation (O, N, S and C glycosides and other derivatives at C-1)
3.1.2 Reactions at Non-anomeric Centres
3.1.2.1 Hydroxyl derivatives protecting groups
3.2 DERIVED SUGARS
3.2.1 Unsaturated Sugars (Glycenoses, Glycenitols) and Their Derivatives
3.2.2 Deoxy Sugars
3.2.3 Amino (Aminodeoxy) Sugars
3.2.4 Anhydrosugars
3.2.5 Branched-chain Sugars
3.2.6 Halogenated (Halogendeoxy) Sugars
3.3 ALDITOLS, CYCLITOLS, CARBOXYLIC AND OTHER ACIDS
3.4 HETEROSUGARS
3.4.1 Carbasugars (and C-Glycosides, section 3.1.1.3)
3.4.2 Thiosugars and Derivatives
3.4.3 Azasugars
3.5 PROPERTIES AND REACTIONS OF OLIGOSACCHARIDES
3.5.1 Disaccharides
3.5.1.1 Sucrose
3.5.1.2 Lactose and lactosamine
3.5.1.3 Maltose (and maltodextrins)
3.5.2 Cyclodextrins
3.6 REACTIONS OF POLYSACCHARIDES AND GLYCOCONJUGATES
3.6.1 Hydrolysis and Other Degradative Processes
3.6.2 Derivatives of Polysaccharides
3.6.2.1 Etherification
3.6.2.2 Esterification
3.6.2.3 Other modifications
3.6.3 Controlled Depolimerization